32 bit Windows
"C:\Program Files\Skype\Phone\Skype.exe" /secondary
64 bit Windows"C:\Program Files (x86)\Skype\Phone\Skype.exe" /secondary
If you always need 2 or more Skype Account to be opened
Right click --> Create shortcut -->
![](http://3.bp.blogspot.com/-0QBUzvaCzPk/Tt7niuw0JJI/AAAAAAAABY4/LJY-fcrPNB8/s320/Multiple+Skype+2.jpg)
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Give it a Name , and a shortcut to open Multiple Skype is done
Hope it helps